Bis(μ-N-benzyl-N-methyl­dithio­carbamato)-1:2κ3 SS′:S′;1:2κ3 S:SS′-bis­bis­(N-benzyl-N-methyl­dithio­carbamato-κ2 SS′)thallium(III)

摘要

The molecule of the dinuclear title compound, [Tl2(C9H10NS2)6], possesses a crystallographically imposed centre of symmetry. Each Tl^III atom is seven-coordinated by S atoms of four different dithio­carbamate anions in a distorted penta­gonal-bipyramidal coordination geometry. The crystal structure is stabilized by a C—H⋯S hydrogen-bond inter­action linking complex mol­ecules into chains running parallel to the b axis. Intramolecular C—H⋯S hydrogen bonds are also present.