catena-Poly(dimethylmalonato-κ2 O:O′)(perchlorato-κO)copper(II)-μ-bis(3-pyridylmethyl)piperazinediium-κ2 N 1′:N 4′ perchlorate dihydrate

机译：阳离子多聚体（二甲基丙二酸-κ2 O：O）（高氯根-κO）铜（II）-μ-双（3-吡啶基甲基基）哌嗪二鎓-κ2 ñ 1′：N 4高氯酸盐二水合物

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In the title compound, {[Cu(C5H6O4)(ClO4)(C16H22N4)]ClO4·2H2O}n, square-pyramidally coordinated Cu atoms with perchlorate and dimethylmalonate ligands are connected into cationic sinusoidal coordination polymer chains by doubly protonated bis(3-pyridylmethyl)piperazine (3-bpmp) ligands. The chains aggregate into pseudo-layers parallel to the (101) crystal planes by N—H⋯O hydrogen bonding. Unligated perchlorate anions and water molecules of crystallization provide additional hydrogen bonding between pseudo-layers.

机译：在标题化合物{[Cu（C5H6O4）（ClO4）（C16H22N4）] ClO4·2H2O} n中，带有高氯酸盐和二甲基丙二酸酯配体的方形金字塔配位的Cu原子通过双质子化双（3-吡啶基甲基）哌嗪（3-bpmp）配体。链通过NHOH氢键聚集成平行于（101）晶面的伪层。未连接的高氯酸根阴离子和结晶水分子在伪层之间提供了额外的氢键。

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期刊名称 Acta Crystallographica Section E: Crystallographic Communications
作者
Gregory A. Farnum; Robert L. LaDuca;
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作者单位

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年(卷),期 2008(64),Pt 12
年度 2008
页码 m1524
总页数 15
原文格式 PDF
正文语种
中图分类生化遗传学;生化药理学;
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专利

1. catena-Poly[[[(dimethylmalonato-κ2O:O′)(perchlorato-κO)copper(II)]-μ-bis(3-pyridylmethyl)piperazinediium-κ2N1′:N4′] perchlorate dihydrate] [J] . Farnum G.A., LaDuca R.L. Acta Crystallographica Section E: Crystallographic Communications . 2008,第12期

机译：链状多聚[[[（（二甲基丙二酸-κ2O：O'）（高氯根-κO）铜（II）]-μ-双-（3-吡啶基甲基）哌嗪二鎓-κ2N1'：N4']高氯酸盐二水合物]
2. catena-Poly[[[(dimethylmalonato-κ2O:O′)(perchlorato-κO)copper(II)]-μ-bis(3-pyridylmethyl)piperazinediium-κ2N1′:N4′] perchlorate dihydrate] [J] . Farnum G.A., LaDuca R.L. Acta Crystallographica Section E: Crystallographic Communications . 2008,第12期

机译：链状多聚[[[（（二甲基丙二酸-κ2O：O'）（高氯根-κO）铜（II）]-μ-双-（3-吡啶基甲基）哌嗪二鎓-κ2N1'：N4']高氯酸盐二水合物]
3. [μ-N,N,N′,N′-Tetra-kis(pyridin-2-ylmeth-yl)butane-1,4-di-amine]-bis--[(di-methanol-κO)(perchlorato-κO)copper(II)] bis--(perchlorate) [J] . Xian-Hong Zhu, Peng Li, Xiao-Wei Chen, IUCrData . 2016,第3期

机译：[μ-N，N，N'，N'-四（吡啶-2-基甲基）丁烷-1,4-二胺]-双-[（二甲醇-κO）（高氯酸盐- κO）铜（II）]双-（高氯酸盐）
4. Fluorescence, computational enactments of dimethyl N,N'-(ethyne-1, 2-di-yl)Bis-(1,4-phenyl-ene carbon-yl)bis-(l-alaninate) crystals [C] . K. Senthil Kannan, P. Thamarikannan, V. Kalaipoonguzhali, International Conference on Physics and Chemistry of Materials in Novel Engineering Applications . 2020

机译：荧光，二甲基N，N' - （乙炔-1,2-二-Y1）双 - （1,4-苯基 - 烯烃碳-Y1）双（L-丙酸盐）晶体
5. Organic sample preparation for femtosecond electron diffraction: Tetra-n-butylammonium triiodide and 1,2-di(2-dimethyl-5-phenylthiophen-3-yl) perfluorocyclopentene. [D] . Elliott, Daniel Craig. 2008

机译：飞秒电子衍射的有机样品制备：四正丁基三碘化铵和1,2-二（2-二甲基-2-苯基-5-苯基噻吩-3-基）全氟环戊烯。
6. catena-Poly[[[bis(N,N-dimethylformamide)iron(II)]-{μ-2,2′-bis(diphenylphosphinoyl)-N,N′-[(1R,2R)-cyclohexane-1,2-diyl]dibenzamide}] bis(perchlorate) N,N-dimethylformamide disolvate] [O] . Grant R. Ferrell, Curtis Moore, Arnold L. Rheingold, 2016

机译：多链[[[[双（N，N-二甲基甲酰胺）铁（II）]]-{μ-2,2'-双（二苯基膦酰基）-N，N'-[（（1R，2R）-环己烷-1,2 -[二基]二苯甲酰胺}]双（高氯酸盐）N，N-二甲基甲酰胺溶解]
7. catena-Poly[[[(dimethylmalonato-κ2 O:O′)(perchlorato-κO)copper(II)]-μ-bis(3-pyridylmethyl)piperazinediium-κ2 N 1′:N 4′] perchlorate dihydrate] [O] . Farnum, Gregory A., LaDuca, Robert L. 2008

机译：阳离子多聚体[[[[（二甲基丙二酸-κ2 O：O'）（高氯根-κO）铜（II）]-μ-双（3-吡啶基甲基基）哌嗪二鎓-κ2 ñ 1′：N 4']高氯酸盐二水合物]

catena-Poly(dimethyl­malonato-κ2 O:O′)(perchlorato-κO)copper(II)-μ-bis­(3-pyridylmeth­yl)piperazinediium-κ2 N 1′:N 4′ perchlorate dihydrate

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catena-Poly(dimethylmalonato-κ2 O:O′)(perchlorato-κO)copper(II)-μ-bis(3-pyridylmethyl)piperazinediium-κ2 N 1′:N 4′ perchlorate dihydrate