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Expanding the biomass derived chemical space

机译:扩大生物质衍生的化学空间

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摘要

Biorefinery aims at the conversion of biomass and renewable feedstocks into fuels and platform chemicals, in analogy to conventional oil refinery. In the past years, the scientific community has defined a number of primary building blocks that can be obtained by direct biomass decomposition. However, the large potential of this “renewable chemical space” to contribute to the generation of value added bio-active compounds and materials still remains unexplored. In general, biomass derived building blocks feature a diverse range of chemical functionalities. In order to be integrated into value-added compounds, they require additional functionalization and/or covalent modification thereby generating secondary building blocks. The latter can be thus regarded as functional components of bio-active molecules or materials and represent an expansion of the renewable chemical space. This perspective highlights the most recent developments and opportunities for the synthesis of secondary biomass derived building blocks and their application to the preparation of value added products.
机译:与常规炼油厂类似,生物炼油厂旨在将生物质和可再生原料转化为燃料和平台化学品。在过去的几年中,科学界已经定义了许多可以通过直接生物质分解获得的主要构件。但是,这种“可再生化学空间”对产生增值生物活性化合物和材料的巨大潜力仍未开发。通常,生物质衍生的构建基块具有多种化学功能。为了整合到增值化合物中,它们需要额外的功能化和/或共价修饰,从而生成二级构件。后者因此可以被认为是生物活性分子或材料的功能成分,代表了可再生化学空间的扩展。该观点突出了合成次级生物质衍生构件及其在制备增值产品中的最新发展和机遇。

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