(577121414-Hexamethyl-14811-tetra­aza­cyclo­tetra­deca-411-diene)nickel(II) bis­OO′-bis­(4-tert-butyl­phen­yl) dithio­phosphate

摘要

The title salt, [Ni(C16H32N4)](C20H26O2PS2)2, comprises a centrosymmetric [Ni(Me6[14]dieneN4)]²⁺ dication (Me6[14]dieneN4 is 5,7,7,12,14,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene) and two O,O′-bis­(4-tert-butyl­phen­yl) dithio­phosphate anions. The Ni^II ion lies on an inversion centre and displays a slightly distorted NiN4 square-planar chelation arrangement with four N atoms from the Me6[14]dieneN4 macrocycle. Two S atoms from symmetry-related anions are located in pseudo-axial positions with respect to the Ni^II ion, with Ni⋯S distances of 3.2991 (7) Å. Inter­molecular N—H⋯S and C—H⋯S hydrogen bonds link the complex cation and pair of anions into a 1:2 type salt.