Poly(aceto­nitrile-κN)-μ3-thio­cyanato-κ3N:S:S-μ2-thio­cyanato-κ2N:S-cadmium

摘要

The asymmetric unit of the title compound, [Cd(NCS)2(CH3CN)]n, consists of one Cd^II cation, two thio­cyanate anions and one aceto­nitrile ligand, all in general positions. The Cd^II cation is coordinated by three N atoms of two thio­cyanate anions and one aceto­nitrile ligand, as well as three S atoms of symmetry-related thio­cyanate anions within a slightly distorted octa­hedral coordination environment. The Cd^II cations are linked by μ-1,3(N,S) and μ-1,1,3(S,S,N) thio­cyanate anions into layers that are located in the ab plane.