Metal(II) Coordination Polymers Derived from Mixed 4-Imidazole Ligands and Carboxylates: Syntheses Topological Structures and Properties

摘要

Four new metal–organic coordination polymers [Cu(L)(mpa)]·3H2O (>1), [Co(L)(mpa)]·H2O (>2), [Zn(L)(mpa)]·H2O (>3), and [Cd(L)(mpa)(H2O)]·H2O (>4) were synthesized by reactions of the corresponding metal(II) salts based on mixed ligands of 1,4-di(1H-imidazol-4-yl)benzene (L) and 4-methylphthalic acid (H2mpa), respectively. The structures of the complexes were characterized by elemental analysis, FT-IR spectroscopy, and single-crystal X-ray diffraction. Compound >1 exhibits a binodal 4-connected three dimensional (3D) architecture with (6⁵·8)->CdSO4 topology, while complexes >2 and >3 are isostructural and have two-dimensional (2D) layer structure with (4, 4) >sql topology based on the binuclear metal subunits. Complex >4 has the same 2D layer structure with (4, 4) >sql topology as complexes >2 and >3, but the inclined interpenetration of parallel sets of layers result in the formation with 2D + 2D → 3D framework. The activated sample >1 shows selective CO2 uptake over N2. The photoluminiscent properties together with quantum yield (QY) and luminescence lifetime are also investigated for complexes >3 and >4 in the solid state at room temperature.