Crystal structure of (5-{3-(1471013-penta­oxa-16-aza­cyclo­octa­decan-16-yl)carbonyl­amino­phen­yl}-101520-tri­phenyl­porphyrinato)cobalt(II)

摘要

In the title compound, [Co(C57H52N6O6)], the central Co^II atom is coordinated by four pyrrole N atoms of the porphyrin core and one O atom of the crown ether. The complex has a distorted porphyrin core, with mean absolute core-atom displacements of 0.14 (10) (C a), 0.20 (10) (C b), 0.24 (4) (C m) and 0.18 (10) Å (C av), respectively. The axial Co—O bond length is 2.3380 (15) and the average Co—Np bond length is 1.968 (5) Å. Intra­molecular N—H⋯O and inter­molecular C—H⋯π inter­actions are observed.