Crystal structure of polydi­aqua­tetra-μ2-cyanido-iron(II)platinum(II) acetone disolvate

摘要

In the title polymeric complex, {[FePt(CN)4(H2O)2]·2C3H6O}n, the Fe^II cation has an octa­hedral [FeN4O2] geometry being coordinated by two water mol­ecules and four cyanide anions. The Pt cation is located on an inversion centre and has a square-planar coordination environment formed by four cyanide groups. The tetra­cyano­platinate anions bridge the Fe^II cations to form infinite two-dimensional layers that propagate in the bc plane. Two guest mol­ecules of acetone per Fe^II are located between the layers. These guest acetone mol­ecules inter­act with the coordinated water mol­ecules by O—H⋯O hydrogen bonds.