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Base-Promoted SNAr Reactions of Fluoro- and Chloroarenes as a Route to N-Aryl Indoles and Carbazoles

机译：氟代和氯代芳烃的碱促进的SNAr反应作为N-芳基吲哚和咔唑的途径

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摘要

KOH/DMSO-promoted C-N bond formation via nucleophilic aromatic substitution (SNAr) between chloroarenes or fluoroarenes with indoles and carbazole under transition metal-free conditions affording the corresponding N-arylated indoles and carbazoles has been developed.

机译：在无过渡金属的条件下，通过吲哚和咔唑之间的氯芳烃或氟代芳烃之间的亲核芳香族取代（SNAr），KOH / DMSO促进了C-N键的形成，从而提供了相应的N-芳基化吲哚和咔唑。

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期刊名称 Molecules
作者
Muhammad Asif Iqbal; Hina Mehmood; Jiaying Lv; Ruimao Hua;
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作者单位

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年(卷),期 2019(24),6
年度 2019
页码 1145
总页数 11
原文格式 PDF
正文语种
中图分类分子生物学;
关键词
base-promoted SNAr haloarene substitution N-arylation of indoles and carbazole;

机译：碱促进的SNAr;卤代芳烃取代;吲哚和咔唑的N-芳基化;

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1. Base-promoted, CBr_4-mecliatecl tandem bromination/intramolecular Friedel-Crafts alkylation of N-aryl enamines: a facile access to 1H- and 3H-indoles [J] . Lan Zhao, Changfu Qiu, Lixin Zhao, Organic & biomolecular chemistry . 2021,第24期

机译：基础促进，CBR_4-MECLIATECL串联溴化溴溴化/分子内的Friedel-Crafts N-芳基酯的烷基化：易于获得1H-和3H-INDOLES
2. 1-Naphthol Synthesis through Base-Promoted SNAr Reactions of ortho-Haloacetophenones Followed by Lewis-Acid-Catalyzed Cyclization [J] . Yu Xiaoqiang, Zhu Peihong, Bao Ming, Asian Journal of Organic Chemistry . 2016,第5期

机译：通过邻卤代苯乙酮的碱促进的SNAr反应后路易斯酸催化的环化反应合成1-萘酚
3. ANIONIC [4+2] CYCLOADDITION REACTIONS OF INDOLE-2,3-DIENOLATE WITH DIENOPHILES - A FACILE REGIOSPECIFIC ROUTE TO SUBSTITUTED CARBAZOLES [J] . Rao MVB., Ila H., Junjappa H., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第19期

机译：吲哚-2,3-二羟吲哚与二甲腈的阴离子[4 + 2]环化反应-取代的咔唑的局部区域特异性路线
4. Stereoselective Synthesis of Axially ChiralC-N Bonds in N-Aryl Indoles and Acridanes [C] . Ken Kamikawa, Akiyoshi Mori, Shunsuke Kinoshita Symposium on Organometallic Chemistry . 2008

机译：基于芳基吲哚和吖啶碱基轴向Chiralc-N键的立体选择性合成
5. Studies on multicomponent reactions: New 4- and 5-component routes to aminoacid diamides and 3-component routes to substituted indoles by modification of the classical Ugi and Fischer indole reactions. [D] . Simoneau, Christopher Allen. 2007

机译：多组分反应的研究：通过改良经典的Ugi和Fischer吲哚反应，新的4和5组分途径可生成氨基酸二酰胺，而3组分途径可生成取代的吲哚。
6. Quinazolinone Synthesis through Base-Promoted SNAr Reactionof ortho-Fluorobenzamides withAmides Followed by Cyclization [O] . MuhammadAsif Iqbal, Le Lu, Hina Mehmood, 2019

机译：碱促进的SNAr反应合成喹唑啉酮邻氟苯甲酰胺与酰胺后环化
7. Base-Promoted SNAr Reactions of Fluoro- and Chloroarenes as a Route to N-Aryl Indoles and Carbazoles [O] . Muhammad Iqbal, Hina Mehmood, Jiaying Lv, 2019

机译：基础促进氟 - 和氯化的鼻窦反应作为碳芳基吲哚和咔唑的途径

Base-Promoted SNAr Reactions of Fluoro- and Chloroarenes as a Route to N-Aryl Indoles and Carbazoles

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