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Particle Surface Softening as Universal Behaviour during Flash Sintering of Oxide Nano-Powders

机译:氧化物纳米粉快速烧结过程中颗粒表面软化作为通用行为

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摘要

The dissipated electric power in oxide powder compacts, subjected to flash sintering, is several hundreds of W·cm−3. This power is analyzed considering local softening/melting and transient plasma/liquid formation at the particle contacts due to thermal runaway. The sudden increase in compact electric conductivity and dissipated power referred to current percolation through the softening/liquid formed at the particle contacts, at the percolation threshold. The energy-balance and heat transfer considerations during the transient flash event are consistent with the local heating of the nanoparticle contacts to the ceramic melting temperature, or above it. The formation of the plasma by field emission of electrons is also considered.
机译:进行快速烧结的氧化物粉末成形体的耗散功率为数百W·cm -3 。考虑到由于热失控而在颗粒接触处发生局部软化/熔化以及瞬态等离子体/液体形成的情况,对该功率进行了分析。紧密电导率和耗散功率的突然增加是指在渗透阈值处通过在颗粒接触处形成的软化/液体的电流渗透。在瞬时闪光事件期间的能量平衡和热传递考虑与纳米颗粒接触部的局部加热至陶瓷熔化温度或高于陶瓷熔化温度一致。还考虑了通过电子的场发射形成等离子体。

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