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Nanocomposites Based on Thermoplastic Polymers and Functional Nanofiller for Sensor Applications

机译:基于热塑性聚合物和功能性纳米填料的纳米复合材料用于传感器应用

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摘要

Thermoplastic polymers like polyolefins, polyesters, polyamide, and styrene polymers are the most representative commodity plastics thanks to their cost-efficient manufacturing processes, excellent thermomechanical properties and their good environmental compatibility, including easy recycling. In the last few decades much effort has been devoted worldwide to extend the applications of such materials by conferring on them new properties through mixing and blending with different additives. In this latter context, nanocomposites have recently offered new exciting possibilities. This review discusses the successful use of nanostructured dispersed substrates in designing new stimuli-responsive nanocomposites; in particular, it provides an updated description of the synthetic routes to prepare nanostructured systems having the typical properties of thermoplastic polymers (continuous matrix), but showing enhanced optical, conductive, and thermal features dependent on the dispersion topology. The controlled nanodispersion of functional labeled clays, noble metal nanoparticles and carbon nanotubes is here evidenced to play a key role in producing hybrid thermoplastic materials that have been used in the design of devices, such as NLO devices, chemiresistors, temperature and deformation sensors.
机译:诸如聚烯烃,聚酯,聚酰胺和苯乙烯聚合物之类的热塑性聚合物是最具代表性的商品塑料,这归因于其具有成本效益的制造工艺,出色的热机械性能以及良好的环境兼容性,包括易于回收利用。在过去的几十年中,世界范围内已经进行了许多努力,以通过与不同添加剂混合和共混赋予它们新的性能来扩展这种材料的应用。在后一种情况下,纳米复合材料最近提供了新的令人兴奋的可能性。这篇综述讨论了纳米结构的分散基质在设计新的刺激响应性纳米复合材料中的成功应用。特别是,它提供了合成路线的更新描述,以制备具有热塑性聚合物(连续基体)的典型特性的纳米结构体系,但显示出取决于分散拓扑的增强的光学,导电和热学特征。事实证明,功能性标记粘土,贵金属纳米颗粒和碳纳米管的受控纳米分散在生产已用于设备设计(例如NLO设备,化学电阻器,温度和变形传感器)的混合热塑性材料中起着关键作用。

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