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Thermal and Mechanical Behavior of Hybrid Polymer Nanocomposite Reinforced with Graphene Nanoplatelets

机译:石墨烯纳米片增强杂化聚合物纳米复合材料的热力学行为

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摘要

In the present investigation, we successfully fabricate a hybrid polymer nanocomposite containing epoxy/polyester blend resin and graphene nanoplatelets (GNPs) by a novel technique. A high intensity ultrasonicator is used to obtain a homogeneous mixture of epoxy/polyester resin and graphene nanoplatelets. This mixture is then mixed with a hardener using a high-speed mechanical stirrer. The trapped air and reaction volatiles are removed from the mixture using high vacuum. The hot press casting method is used to make the nanocomposite specimens. Tensile tests, dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA) are performed on neat, 0.2 wt %, 0.5 wt %, 1 wt %, 1.5 wt % and 2 wt % GNP-reinforced epoxy/polyester blend resin to investigate the reinforcement effect on the thermal and mechanical properties of the nanocomposites. The results of this research indicate that the tensile strength of the novel nanocomposite material increases to 86.8% with the addition of a ratio of graphene nanoplatelets as low as 0.2 wt %. DMA results indicate that the 1 wt % GNP-reinforced epoxy/polyester nanocomposite possesses the highest storage modulus and glass transition temperature (Tg), as compared to neat epoxy/polyester or the other nanocomposite specimens. In addition, TGA results verify thethermal stability of the experimental specimens, regardless of the weight percentage of GNPs.
机译:在本研究中,我们通过一种新技术成功地制备了一种包含环氧/聚酯共混树脂和石墨烯纳米片(GNP)的杂化聚合物纳米复合材料。高强度超声仪用于获得环氧/聚酯树脂和石墨烯纳米片的均匀混合物。然后使用高速机械搅拌器将此混合物与硬化剂混​​合。使用高真空从混合物中除去残留的空气和反应挥发物。热压铸法用于制备纳米复合材料样品。对纯,0.2 wt%,0.5 wt%,1 wt%,1.5 wt%和2 wt%GNP增强的环氧/聚酯共混树脂进行拉伸测试,动态力学分析(DMA)和热重分析(TGA),以研究增强对纳米复合材料的热和机械性能的影响。这项研究的结果表明,通过添加低至0.2 wt%的石墨烯纳米片比例,新型纳米复合材料的拉伸强度提高至86.8%。 DMA结果表明,与纯环氧/聚酯或其他纳米复合材料样品相比,GNP含量增强1%的环氧/聚酯纳米复合材料具有最高的储能模量和玻璃化转变温度(Tg)。此外,TGA结果验证了实验样品的热稳定性,而与GNP的重量百分比无关。

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