首页> 美国卫生研究院文献>Acta Crystallographica Section E: Crystallographic Communications >2-(5-Bromo­thio­phen-2-yl)-5-[5-(10-ethyl­phenothia­zin-3-yl)thio­phen-2-yl]-1,3,4-oxadiazole
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2-(5-Bromo­thio­phen-2-yl)-5-[5-(10-ethyl­phenothia­zin-3-yl)thio­phen-2-yl]-1,3,4-oxadiazole

机译:2-(5-溴噻吩并-2-苯基)-5- [5-(10-乙基噻吩并嗪-3-基)噻吩-2-基] -1,3,4-恶二唑

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摘要

The mol­ecule of the title compound, C24H16BrN3OS3, contains three approximately planar fragments, viz. an oxadiazole ring plus two adjacent thio­phene groups, and two phenothia­zine benzene rings, with largest deviations from the least-squares planes of 0.051 (3), 0.019 (4) and 0.014 (3) Å, respectively. The phenothia­zine unit adopts a butterfly conformation, with a dihedral angle of 38.06 (15)° between the terminal benzene rings. The dihedral angle between the 2,5-bis­(thio­phen-2-yl)oxadiazole unit and the attached benzene ring is 15.35 (11)°. In the crystal, mol­ecules form stacks along the b-axis direction; neighboring mol­ecules within the stack are related by inversion centers, with shortest inter­centroid separations of 3.741 (2) and 3.767 (2) Å.
机译:标题化合物C24H16BrN3OS3的分子包含三个近似平面的片段,即。一个恶二唑环加上两个相邻的噻吩基和两个吩噻嗪苯环,它们与最小二乘平面的最大偏差分别为0.051(3),0.019(4)和0.014(3)Å。吩噻嗪单元呈蝶形,末端苯环之间的二面角为38.06°(15)°。 2,5-双­(硫代­吩-2-基)恶二唑单元与连接的苯环之间的二面角为15.35(11)°。在晶体中,分子沿b轴方向形成堆栈;堆栈中相邻的分子与反演中心有关,最短的质心间间隔为3.741(2)和3.767(2)Å。

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