氯化铋在LiCl-KCl熔盐中的电化学行为

摘要

This work study the the electrochemical behavior of BiCl3 in the BiCl3-LiCl-KCl molten salt on an inert tungsten electrode.The reduction process of Bi3+ was studied by cyclic voltammetry in molten salt, and the number of transferred electron was calculated.The potentiostatic electrolysis was employed to study the deposition behavior of Bi on an inert tungsten, than the deposits were identified by X-ray diffraction (XRD).%研究了BiCl3-Li-KCl熔盐中BiCl3在钨电极上的电化学行为,采用循环伏安法研究了Bi3+在熔盐中的还原过程,并计算了转移电子数,采用恒电位沉积法研究了铋在钨电极上的沉积行为,并用XRD对沉积产物进行了表征.