Rheological experiments under steady and oscillatory shear were conducted for fumed silica suspen- sions in polyethylene glycol. Under steady shear the shear-thinning and thickening response were exhibited and the flow exponent N was determined. With the increase of concentration the flow exponent N showed a rapid increase, and it increased dramatically when the discontinuous shear-thickening took place. Oscillatory shear experiments were conducted at constant frequency and constant amplitude strain, respectively. The shear-thinning and the discontinuous shear-thickening behavior were observed under different constant frequencies from 10 to 80 rad/s. The correlation between complex modulus (G*) and sweep frequency (ω) was illuminated at γ =750%. It was found that the correlation between G* and ω could be fitted by equation: G*∝ωn. The indexes in shear-thinning region and shear-thickening were determined. The indexes were similar to some extent at shear-thinning region and increased dramati- cally to a much higher value when the shear-thickening occurred,especially at higher weight fractions. The behaviors can be qualitatively explained as follows: the shear-thinning owes to decrease of viscos- ity, which results from disruption of the aggregates; the cluster theory attributes the shear-thickening to the formation of metastable, flow induced clusters, which block the system.
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机译:Changes in the Physical and Mechanical Properties of Human Blood with Sustained Prophylactic Use of Acetylsalicylic Acid (Aspirin)—A Rheological Study