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石门磷精矿用于窑法磷酸生产原料的评价实验

         

摘要

An evaluation experiment was conducted for a kind of Shimen phosphorus concentrate which was obtained after the process of roasting-digestion-solid/liquid separation. Results showed that pelletizing with calcium to silicon at a ratio of 0.30, addition of carbon at an amount of 1.5 times theoretical value, resulted in the green pellets with compressive strength at 34.5 N and drop strength over 22 times at 0.5 m, dry pellets with compressive strength at 203.5 N and drop strength at 1 m over 5.2 times, presenting a good pelletization. The reduction of phosphate concentrate at 1360 ℃ for 40 min, with calcium to silicon at a ratio of 0.37, carbon addition at an amount of 1.5 times theoretical value, led to the phosphorus reduction rate up to 96% and slag ball with good meltability. Test results indicate that Shimen phosphorus concentrate is a good raw material for kiln phosphoric acid production.%对采用焙烧-消化-分离得到的石门磷精矿进行了评价实验,结果表明,在钙硅比0.30、配碳量为理论量的1.5倍条件下配料、造球,生球抗压强度34.5 N、0.5 m落下强度大于22次,干球抗压强度203.5 N、1 m落下强度大于5.2次,球团性能良好.磷精矿在钙硅比0.37、配碳量为理论量的1.5倍、1360℃下还原40 min,磷还原率达到96%,渣球软熔性好.实验表明,石门磷精矿是一种适合窑法磷酸工艺的生产原料.

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