两个3,3'-偶氮联吡啶配合物的合成和性质的研究

摘要

合成了两个3,3'-偶氮联吡啶配合物{[Cu(NO3)2(H2O)2(3,3'-azpy)2](1)和{[Mn(H2O)4(3,3'-azpy)](3,3'-azpy)3(PF6)2}n(2),并且用元素分析、红外和变温磁化率进行了表征.在75～300K的变温磁化率研究表明化合物(1)和(2)都遵守Curie-Weiss定律.%The complexes {[Cu(NO3)2(H2O)2( 3,3'- azpy)2](1) and {[Mn(H2O)4(3,3'-azpy)] (3,3'-azpy)3(PF6)2} n (2)(3,3'-azpy=3,3'-azobispyridine) were synthesized and characterized by elemental analyses, IR and Variable-temperature magnetic susceptibility. Variable-temperature magnetic susceptibility studies in the temperature range 75～ 300K, showed that the compounds (1) and (2) both obey the Curie-Weiss law.