Present states and recent advances in M-type permanent ferrites are reviewed in this paper. The key te chnology for the manufacturing of M -type ferrites with high performan ces such as pre-sintering, micro-c rushing and magnetic orientating in pres sing with magnetic field is discussed. T his paper has described the promisi ng ideas and processes in order to improve the properties of sintere d M-type magnets in industry in th e future. Commercial high-energy p roduct strontium hexaferrites have in detail been characterized in t ems of their chemical compositions , microstructures, and bulk and su bmicroscopic magnetic properties. 57Fe Mssbauer spectro scopy shows that the magnetic prope rties of nonstoichiometric M-Type ferrites correlates with the relat ive intensity of the pattern assig ned to the 4f1 and 4f2 sites. Th e La2O3 additiion to SrO*6Fe2O 3 is very useful in stabilizing th e magnetoplumbite structure and th ese Sr-La-system ferrites have exc ellent properties as a permanent m agnet. Lanthanum and zinc substitu tion in M-type hexaferrite can ach ieve high orientation degree,high mass density, submicronsized grain s and high saturation magnetizatio n. The Br and (BH)max has greatly advanced in M-type Sr-ferr ites as hoped.%评述了M型永磁铁氧体的现状与进展。讨论了M型永磁铁氧体在工业生产中的 关键技术问题,如预烧工艺、微粉加工、料浆在磁场成型时的取向。详细地调 研了高性能锶铁氧体的化学成分、显微结构、宏观的和亚微观的磁性能。 57Fe Mssbauer谱显示非化学计量的M 型永磁铁氧体性能与4f1与4f2晶位谱线强度相关。La2O3掺杂对 稳定磁铅石结构和提高永磁体性能有益。La3+和Zn2+联 合取代对M型六角铁氧体晶粒取向度、质量密度、亚微米尺寸结构和饱和磁化 强度有明显的作用,正像人们期望的那样,M型锶铁氧体的Br和( BH)max取得了显著的进展。
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