三聚体二苯基锗氧化合物的合成及晶体结构研究

摘要

The tripolymer compound (Ph2GeO)3 has been synthesized with a novel method and characterized by means of X-ray single crystal diffraction. The structure features of the compound are described.%研究了用二苯基二氯化锗的水解反应,得到了三聚体二苯基锗氧化合物,用X-射线晶体衍射确定了结构.配合物为单斜晶体,空间群P21/c.晶体学数据:a=1.001 8(2),b=1.862 4(4),c=1.770 9(4)nm,β=93.49(3)0,V=3 304.0(11)nm3,Z=4,Dcal.=1.464 mg/m3,F(000)=1 464,R1=0.043 8,wR2=0.073.