有机锡化合物{(PhCH2)2Sn4-NC5H4CON2C(CH3)CO2(H2O)}2的合成及晶体结构

摘要

合成了有机锡化合物{(PhCH2)2Sn[4-NC5H4CON2C(CH3)CO2](H2O)}.用X-射线单晶衍射测定了该化合物的晶体结构,结果表明,在该配合物的晶体中,锡原子呈五配位畸变三角双锥构型.%The {(PhCH2)2Sn[4-NC5H4CON2C(CH3)CO2](H2O)} has been prepared and determined by X-ray single crystal diffraction.The structures show that the tin atoms of the compound is rendered seven-coordinated in distorted pentagonal bipyramid geometries with a planar SnO4N unit and two apical aryl carbon atoms.