设计制作了多种空芯光纤探头,搭建了基于傅里叶变换红外光谱仪的遥测系统.实验结果表明,采用锥形耦合光纤为接收光纤的探头具有17.6％的高效系统传输效率.对聚碳酸酯、聚偏二氟乙烯等有机物和无水乙醇、甲苯等有机溶剂薄膜的光谱进行测量,得到了遥测光谱.根据甲苯在1605 cm-1波数的特征峰对甲苯/乙醇混合溶液中的甲苯浓度进行定量遥测分析.配置浓度在5％～50％的多份混合溶液用于建立定量模型,并独立检验.结果显示检验的预测均方根误差(RMSEP)为3.356,参考值和预测值的相关系数为0.9200.初步实现了对薄膜、混合溶液等进行红外特征谱的遥测.%Infrared probes composed of different hollow fibers were designed, fabricated, and optimized. Remote measuring system using the probe was set up with a Fourier Transform Infrared Spectrometer (FTIR). The experimental results showed that the transmission efficiency reached 17. 6% when tapered fiber was used as the receiving fiber in the probe. Infrared spectral features were measured for films such as polycarbonate (PC) and Poly vinylidene fluoride (PVDF), as well as liquid-phase films such as ethanol and toluene. Quantitative measurements were carried out for the mixed liquid of ethanol and toluene using the characteristic absorption peak of toluene at the wavenumber of 1605 cm-1. A number of mixed liquid with various concentration ranging from 5% to 50% were made to build the quantitative model and evaluate the effect of the measurement. The results showed that RMSEP was 3.356 and the correlation coefficient was 0. 9200. The system can be used in remote sensing of spectral features for solid and liquid phase films.
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