The structural feature of equalizing coordinate complex, mixed coordinate complex and big cyclic polymer with dithiolene forming was analysed. The relation between structure and property was research. The functional characteristic of the superconductivity, electric conductivity, semicon ductivity, photoconductivity, photosensitivity, gas sensitivity, fluorescence, photorecord, nonlinear optics, electrochemical catalysis, magnetism and so on of the title complexes and polymer were revealed.%分析了二硫纶体系中均配配合物、混配配合 物和大环聚合物的结构特点,探讨了它们的结构与性质之间的关系,揭示了这类配合物和聚 合物所具有超导、电导、半电导、光电导、光敏、气敏、荧光、光记录、非线性光学、电化 学催化及磁性等功能性的本质特征。
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