富勒烯化学开笼的研究进展

摘要

系统地阐述了当前富勒烯化学开笼的研究进展情况,并重点介绍了叠氮化富勒烯衍生物的制备方法,此外,还介绍了重氮化,氮杂环化学开笼,单线态氧化,以及硫化等化学开笼方法。%The advances in chemistry ring-opening of the fullerene were reviewed,especially the method of preparing aza-fullerenes derivatives,including the reaction of diazo fullerenes,azotic heterocyclic,singlet oxygen,and sulfide.