为解决电化学法处理高盐染料废水存在的能耗大、成本高等问题,分别采用溶胶-凝胶法和辊压法制备Ti/SnO2-Sb阳极和空气阴极,构建了Ti/SnO2-Sb阳极-空气阴极双极体系(TSSA-ADC).甲基橙(MO)作为高盐染料废水的典型污染物,考察了电流强度、MO浓度、电解液浓度和初始pH对TSSA-ADC体系和TSSA单阳极体系降解MO的影响.结果表明:与TSSA单阳极体系相比,TSSA-ADC体系具有更好的抗有机负荷冲击、抗盐分冲击、抗酸碱波动能力,能够维护酸碱平衡防止硬度离子结垢.最佳反应条件为电流强度为0.030 A,电解液浓度为3%,MO浓度为100 mg/L,初始pH =6.以MO去除率达到98%为基准,TSSA-ADC体系比TSSA体系可节能74.26%.%Electrochemical technology for dye pollutant purification from high salinity wastewater are sufferring from high cost and energy consumption.To overcome these problems,a Ti/SnO2-Sb anode (TSSA)-air diffusion cathode (TSSA-ADC) system was established,where the anode was prepared by a sol-gel method and the air cathode was prepared by a roiling method.By using methyl orange (MO) as the target pollutant,the influence of the operational parameters,including current intensity,initial MO concentration,electrolyte concentration and initial pH,were investigated.The results showed that the TSSA-ADC system possessed higher resistivity to the fluctuation of organic load,salt,acid and alkali and had stronger ability in anti-scaling than the TSSA system.The optimal MO removal effect was obtained with 100 mg/L MO in 3% NaCl solution at the current of 0.03A as well as initial pH value of 6.As to the MO removal efficiency of 98%,the energy consumption was reduced by 74.26% in the TSSA-ADC system compared to the TSSA system.
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