A series of compositionally complex fluorite oxides(CCFOs)were prepared by ball milling the mixture of ZrO_(2),HfO_(2),Y_(2)O_(3),La_(2)O_(3),and Pr_(6)O_(11)followed by conventional solid-state sintering.Both XRD and TG-DSC results demonstrated that single-phase(Zr_(0.2)Hf_(0.2)Pr_(0.2)Y_(0.2)La_(0.2))O_(2-)δwas formed at 1400°C.Elements in bulk ceramic were uniformly distributed without evident accumulation according to SEM-EDS pictures.TEM results revealed that polycrystalline ceramic powder was assignable to cubic Fm-3m fluorite structure.The electrical conductivity(σ)was measured via EIS technology and activation energy(E_(a))of CCFOs was calculated in Arrhenius plots.In the temperature range of 300-750°C,CCFOs preserved the same conduction mechanism and(Zr_(0.1667)Hf_(0.1667)Pr_(0.1667)Y_(0.25)La_(0.25))O_(2-)δpossessed higherσand lower E_(a) than other high entropy fluorite oxides which is related to the incorporation of Pr element or the connection of cation-V_(o) complex.
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机译:Preparation and dielectric properties of lead-free perovskite-structured high-entropy ceramics of (La0.25Sr0.25Ba0.25Na0.25)(Ti0.5Me0.5)O3-δ (Me=Sn, Zr, Hf) via doping at both A and B sites
机译:Preparation and effect of grain size on the thermal stability, phase transition, mechanical property, and photocatalytic property of pyrochlore (La0.2Nd0.2Sm0.2Gd0.2Y0.2)2Zr2O7 high-entropy oxide