The Sr3Tl5 phase was prepared by high temperature synthesis techniques through reaction of the high purity elements in the welded Nb tubes.The structure established through X-ray structural analysis shows the compound is a good hypoelectronic trielide example of the Pu3Pd5 structural type in which skeletal electron count is lower than in a traditional Zintl phase(Cmcm,Z = 4;a = 10.604(2) ,b = 8.675(2) ,and c = 10.985(2) ;V = 1010.5(3) 3).The strontium size and the compound's polarity appear responsible for this thallium phase crystallization in the Pu3Pd5 family type rather than the isoelectronic Sr3In5 version.A first-principle electronic structure calculation(LMTO) demonstrates that the strontium atoms participate substantially in Sr-Tl bonding in the structure.
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机译:1-Benzyl-4-(4-nitrophenyl)-2,3-dihydro-1H-1,5-benzodiazepine: a three-dimensional framework structure generated by two C-H...O hydrogen bonds and one C-H...pi(arene) hydrogen bond.
机译:1-Benzyl-4-(4-nitrophenyl)-2,3-dihydro-1H-1,5-benzodiazepine: a three-dimensional framework structure generated by two C-H center dot center dot center dot O hydrogen bonds and one C-H center dot center dot center dot pi(arene) hydrogen bond
机译:1-Benzyl-4-(4-nitrophenyl)-2,3-dihydro-1H-1,5-benzodiazepine: a three-dimensional framework structure generated by two C-H...O hydrogen bonds and one C-H...pi(arene) hydrogen bond.
机译:studies on asymmetric syntheses of Benzophenanthridine alkaloids and the Related spiro Compounds: studies on Chelidonine synthesis and Total synthesis of arnottins I and II