Sm/AlCl3·6H2O体系促进的叠氮化合物的化学选择性还原:一种制备胺的新方法

摘要

In the presence of metallic samarium-aluminum( Ⅲ ) chloride hexahydrate, azides can be reduced to corresponding amines in high yields under mild and neutral conditions.%在金属钐和六水合三氯化铝的存在下,叠氮化合物能在温和及中性条件下高产率地被还原为相应的胺.