6-溴-7-异丙基-1,10-二甲基-1,2,3,4-四氢蒽-1-羧酸的合成

摘要

A new four hydrogen anthracene carboxylic acid derivative,(R)-6-bromo-7-isopropyl-1,10-dimethyl-1,2,3,4-tetrahydroanthracene-1-carboxylic acid,was synthesized by esterification,bromination,oxidation,isomerization and hydrolysis reaction from dehydroabietic acid.The structure was characterized by 1H NMR,13C NMR,IR,ESI-MS and elemental analysis.%以脱氢松香酸为原料,经酯化、溴代、氧化、异构化、水解等反应,合成了一种新型的四氢蒽羧酸类衍生物——6-溴-7-异丙基-1,10-二甲基-1,2,3,4-四氢蒽-1-羧酸,其结构经1H NMR,13C NMR,MS和元素分析表征.