含碳铬铁矿球团的固态还原特性

摘要

通过含碳铬铁矿粉矿成球及还原实验,研究还原温度、内配碳量、还原时间和添加剂对铬铁矿球团预还原结果的影响.结果表明:还原温度和内配碳量对预还原球团的金属化指标影响非常明显,温度高于1200℃时,铬铁矿预还原球团的金属化指标开始明显增加,内配碳比Ic/o=1.2为铬铁矿预还原球团的较佳配比;高温(≥1 300℃)时,可实现含碳铬铁矿球团的快速还原(f≤1 h);低温时,铁优先于铬还原,总还原反应完成时间需3~4 h.添加剂强化含碳铬铁矿球团预还原的实验结果表明,不同添加剂对还原反应的影响具有较大差异;不同温度下,相同添加剂的催化能力也有一定的差异;实验所涉及的添加剂中以NaCl、Na2B4O7·10H2O和Na2CO3的催化效果较好.%The bailing and reducing experiments of carbon-bearing chromite fines were carried out in laboratory. The effects of reduction temperature, amount of carbon, reduction time and types of additives on the metallization of carbon-bearing chromite pellets were investigated. The results show that the reductivity of carbon-bearing chromite pellet is greatly influenced by the reduction temperature and C/O mole ratio. At the temperature above 1 200 ℃, the metallization of prereduction pellet begins to increase obviously, and Ic/o=1.2 is better for the prereduetion of chromite pellet. The fast reduction of carbon-bearing chromite pellet can be achieved at high temperature (≥ 1 300 ℃); but it needs 3-4 h to finish the reduction reaction at low temperature, and the reduction reaction of iron is easier than that of chromium. The intensifying reduction of carbon-bearing chromite pellet with the help of additives was studied. The results indicate that different additives have great difference in the influence of reduction reaction, and the catalytic property of the same additive also has some difference at different reduction temperatures. For all involved additives in the experiment, NaCl, Na2B4O7· 10H2O and Na2CO3 have excellent catalytic performance.