The novel bismuth(Ⅲ)compex with dithiotetrahydropyrrolocarbamate ,[Bi(S2CNC4H8)3]2 has been synthesized.The crystal structure has been determined by X-ray single crastal diffraction .The crystal bilongs to monoclinic with space guoup C2/c,a=1.6356(9)nm,b=1.1875(6)nm,c=2.3954(13)nm,β=100.741(8)°,Z=4,V=4.571(4)nm3,Dx=1.882g@cm-3,μ=8.267mm-1,F(000)=2512,R=0.0404,wR=0.0622.In this bunuclear complex ,each Bi(Ⅲ)is seven coordinate with a distorted pentagonal bipyramidal geometry .CCDC:179924.
展开▼
