一维链配位聚合物Mn(acacen){N(CN)2}n的合成、结构和性质的研究

摘要

The manganese(Ⅲ) complex [Mn (acacen) {N (CN)2}]n [H2acacen =bis (acetylacetone)ethylenediimine] has been synthesized and the structure has been determined. The complex forms a one-dimensional chain structure via the bidentate bridge ligandμ1,5-[N(CN)2]- linking [Mn(acacen)] moiety. The magnetic property of the compound (75～300 K) shows the existence of an antiferromagnetic exchange interaction among paramagnetic centers along the chain. CCDC: 244940.