气相色谱-紫外分光光度法研究含能配合物-M(CHZ)3 (TNM)2的爆炸气体产物

摘要

以[M(CHZ)3](TNM)2(M分别为Pb、Zn、Ni和Cd)4种三硝基甲烷系列配合物的爆炸气体产物为研究对象,采用气相色谱-紫外分光光度法定性和定量分析了爆炸产物中N2、CO、C02、NOx、NH3及CH4等6种常量气体产物.结果表明,三硝基甲烷系列化合物的爆炸气体中常量气体产物N2含量最高,CO次之,CH4含量最少；并且NOx及NH3含量均小于标准规定.%The contents of N2 ,CO,CO2 .NO, ,NH3 and CH4 as explosion gas products of trinitromethane compounds ([M(CHZ)3](TNM)2 (M=Pb,Zn,Ni and Cd)) are measured by gas chromatograph and ultraviolet spectrophotom-etry. The results show that the content of N2 is the highest in the normal explosive gases .followed by CO, and the content of CH4 is the least. The content of NOX and NH3 is less than the standards.