以富马酸二叔丁基酯和2,2-双(p-二甲基-氯硅氧基苯)丙烷为单体,通过缩聚合成得到聚[富马酸-2,2-双(p-二甲基硅氧烷-苯基)丙烷硅基酯],采用核磁共振氢谱、差示扫描量热法、热失重分析和凝胶渗透色谱表征了聚合物.结果表明,该聚合物的重均分子量为6 912,聚合度为15.6,玻璃化转变温度为16.7℃,具有良好的热稳定性,且在48 h基本降解完全.%Poly( fumaric acid silyl ester) was synthesized by polycondensation of di-tert-butyl fumarate with 2,2-bis ( p-chlorodimethylsiloxy-phenyl ) propane. The polymer was characterized by 1H-nuclear magnetic resonance, differential scanning calorimetry, thermogravimetric analysis andgel permeation chromatography. The results showed that the weightaverage molecular weight and polymerization degree were 6 912, 15.6, respectively. The glass transition temperature was 16. 7 ℃, and the thermal stability was good. The polymer degraded completely in 48 h.
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