二氟氨基化合物的合成研究进展

摘要

二氟氨基化合物由于其较高的能量特性在早前已被普遍关注,但很长一段时间并未很好地解决其结构不稳定性。直至20世纪90年代末期,稳定结构的二氟氨基化合物的合成才逐渐取得进展。目前,该领域的研究主要集中在二氟氨基取代氧杂环丁烷、环N-硝胺基偕二氟氨基氧化剂的合成及新型二氟氨基化方法的应用上。%Difluoramino compounds had already been widespread concerned because of its high energy property. Meanwhile, its structure instability has not been solved for a long time. Until the late 1990s, the synthesis of difluoramino compounds with stable structure was gradually made progresses. Now the main research is focused on the synthesis of difluoramino substituted oxctanes, cyclic N-nitramino geminal difluoramino oxidizers, and the applications of new difluoramination methodologies.