研究了不同取代酚与三光气的反应,得到七种未见报道的新化合物,以IR、MS、1 H NMR、13C NMR对产物进行了表征,并探索得到合适的反应催化剂、反应物浓度配比、反应时间,讨论了酚上不同取代基对反应的影响,收率在78.5 ～90.5％之间.%The synthesis of aryl trichloromethylcarbonates from phenols and triphosgene were studied, seven new compounds were synthesized,the products were characterized by IR,MS,'H NMR and 13C NMR. Suitable catalyst,reaction time and reactant ratio were explored and determined,influence on the different substituted group in the phenols were also discussed. The reaction yields were from 78. 5% to 90. 5%.
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