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添加铁粉制备低密度中强度陶粒支撑剂及性能研究

     

摘要

低密度中强度陶粒支撑剂的开发,既可以提高低渗透油气藏的开发效率又能显著降低油气开采成本.以Al2O3含量为63%的二级铝矾土为主要原料,以铁粉取代部分锰矿粉制备了低密度中强度陶粒支撑剂.结果表明:添加铁粉2%,锰矿粉3%、白云石1%时,在1 350℃下煅烧1h,有利于陶粒支撑剂中生成均匀分布的直径为0.3~1.0 μm棒状莫来石晶相,棒状莫来石起到纤维增韧作用,提高支撑剂的强度,使其在52 MPa的闭合压力下破碎率为5.29%,体积密度为1.63 g/cm3.随着铁粉添加量的增加,基体中液相大量增加,晶粒生长速度过快未能有效排除气孔,导致大量气孔包在晶粒之间,容易构成应力集中点而形成裂纹源,降低了支撑剂的密度和强度.%Light-weight middle-strength ceramisite proppant is beneficial to the improvement of productivity of low-permeability oil and gas reservoir,and is able to reduce the cost of oil and gas production significantly.The light-weight middle-strength ceramisite proppant was prepared from bauxite(63 wt% Al2O3) by adding manganese mineral,part of that was replace by iron powder.The results show that strength of ceramisite proppant was improved by rod-like mullite with the diameter of 0.3 ~ 1.0μm,which playa remarkable role in the increment of fracture toughness,when iron powder content is 3 wt%,and manganese mineral content is 2 wt%,and dolomite content is 1 wt% and sintering at 1 350 ℃ for 1 h.The breakage ratio is 5.29% and bulk density was 1.63 g/cm3 under 52 MPa closure pressure.In addition,as the iron powder increase,he liquid phase increase in the matrix,many intergranular closed pores were formed as a result of the grain growth which was too speedy to eliminate pores.It is easy to form the crack source and reduce the density and strength of ceramisite proppant.

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