Characterization of activities of crumb rubber in interaction with asphalt and its effect on final properties.

摘要

Recycling of millions of scrap tires produced everyday is crucial challenge encountered by waste management systems. Recycling tire rubbers in form of ground tire rubber, known as crumb rubber modifier (CRM), in asphalt industry was introduced in early 1960's and is proved as an effective recycling method. Interaction between CRM and asphalt is physical in nature which happens mainly due to exchange of components between CRM and asphalt and enhances the time temperature dependant properties of asphalt.;In this work, the interaction between CRM and asphalt was evaluated through monitoring the evolutions of CRM in asphalt in macro and micro-level. The mechanism and extent of CRM dissolution were monitored under several interaction conditions. The composition of materials released from CRM was investigated using thermo-gravimetric analysis (TGA). The molecular status of the released components were studied using gel permeation chromatography (GPC) analysis. The composition analysis indicated that the CRM start releasing its polymeric components into the asphalt matrix at dissolutions higher than 20%. The released polymeric component of CRM alters the microstructure of the asphalt and creates an internal network at certain interaction temperatures according to viscoelastic analysis. At these temperatures, the released polymeric components are at their highest molecular weight based on GPC results.;The effect of released components of CRM on the time temperature dependent properties of asphalt and its glass transition kinetic was monitored using dynamic shear rheometer (DSR) and differential scanning calorimetry (DSC), respectively. The DSC results showed that the intensity of glass transition of the asphalt binder which is mainly defined by the aromatic components in asphalt reduced by absorption of these components by CRM.;The evolution of CRM was investigated during short-term aging of the modified asphalt binder. In addition, the effect of presence of CRM and release of its component on oxidization of asphalt binder was evaluated using Fourier transform infrared spectroscopy (FTIR). The results revealed that CRM continue absorbing the aromatic components of asphalt during aging which stiffen the asphalt binder. Also, it was observed that release of oily components of the CRM, which contain antioxidant, reduces oxidization rate of asphalt significantly.