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Incorporation of ferrocenesulfoniccarboxylic acid into polyaniline film:Synthesis and applications

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独创性声明及学位论文版权使用授权书

CHAPTER ONE: General introduction

1. Polyaniline as a conducting polymer

1.1. Polyaniline incorporated with electroactive substances

2. Polyaniline as a gas sensor

1.2. Measurement of electrical conductivity changes

1.3. Measurement of an electrochemical parameter

References

CHAPTER TWO: CHAPTER TWO: Influence of ferrocenesulfoniccarboxylic acid on polyaniline electrochemical synthesis and preparation of ferrocene-doped polyaniline bearing functional group

1. Introduction

2. Exprimental

3. Results and discussion

3.1. Electropolymerization of aniline in the presence of Ferrocenesulfoniccarboxylic acid SO3HFcCOOH

3.2. Cyclic voltammogramsof polyaniline synthesized

3.3.UV-Visible studies

3.4. IR studies

3.5. Morphology

3.6. Action of ammonia on the polymer

3.7. Theoretical studies

4. Conclusion

References

CHAPTER THREE: Electrochemical behavior of methanol on polyaniline incorporated withferrocenesulfoniccarboxylic acid

1. Introduction

2. Experimental

3. Results and discussion

4. Conclusion

References

CHAPTER FOUR: Electrocatalytic oxidation without enzyme of theophylline on polyaniline synthesized in the presence of ferrocenesulfoniccarboxylic acid

1. Introduction

2. Experimental

3. Results and discussion

3.1. Electrochemical oxidation of theophylline

3.2. Influence of pH

3.3. Effect of scan rate

3.4. Influence of potential range

3.5. Linearlity, detection limit and the principle of the theophylline sensor

3.6. Sample analysis

4. Conclusion

References

Acknowledgement

在学期间公开发表的论文及著作情况

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摘要

我们的工作重点是用磺酸基二茂铁甲酸掺杂聚苯胺,本论文主要分为三个部分:(1)研究了在磺酸基二茂铁甲酸(SO<,3>HFcCOOH)存在下苯胺的电聚合过程,结果表明在膜电沉积过程中SO<,3>HFcCOOH使聚苯胺质子化.并用IR,UV-Vis光谱和理论计算表征该膜.(2)将得到的聚苯胺膜(PANI-Fc)修饰电极应用在甲醇(CH<,3>OH)的电催化氧化上.在燃料电池方面,这是一个重要的反应.(3)将合成的聚苯胺膜(PANI-Fc)修饰电极应用于茶碱的电催化氧化研究.

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