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Effect of geometry on adsorption in cylindrical nanopores

机译:几何形状对圆柱形纳米孔吸附的影响

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摘要

We consider adsorption of a fluid on a nanopore with noncircular cross section. In a phenomenological theory based on an effective interfacial potential (1), the s hape and thickness of the surface layer is calculated. A preference for adsporption in zones of high curvature of the pore surface is demonstrated with a tendency to formation of a circular effective pore of highly reduced radius(2). The results are verified by a numerical simulation using the Monte Carlo method for a model Lenard Jones fluid.
机译:我们考虑将流体吸附在具有非圆形横截面的纳米孔上。在基于有效界面势(1)的现象学理论中,计算了表层的翘曲和厚度。在孔隙表面高曲率的区域中,吸附倾向于形成半径减小的圆形有效孔隙(2)。使用蒙特卡洛方法对模型Lenard Jones流体进行数值模拟,验证了结果。

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