首页> 外文会议>SPE(Society of Plastics Engineers) Regional Technical Conference on Color and Appearance Division(CAD RETEC 2006); 20060917-19; Cincinnati,OH(US) >Back to the Basics of Organic Pigments: Diketopyrrolopyrrole Pigments as the Model Organic Chromophore
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Back to the Basics of Organic Pigments: Diketopyrrolopyrrole Pigments as the Model Organic Chromophore

机译:回到有机颜料的基础:二酮吡咯并吡咯颜料作为有机发色团的模型

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Since this paper is meant to cover some of the fundamentals of organic pigments, let the start be a thorough understanding of the title itself. First, it is necessary to appreciate that of the entire universe of the color experience we are going to try to understand just a few points about a very small subset of this experience: small, solid, usually crystalline particles which remain insoluble when put into plastic and which selectively absorb light of certain wavelengths (hence appearing to have color). Second, what do we mean by organic? Organic means containing as a basis the element carbon, but then some carbon compounds are excluded. Perhaps this isn't the best of definitions, but a full explanation could be quite lengthy. Inclusion of other elements is necessary to create colored compounds. For the organic colorants, the most likely other elements present are nitrogen, oxygen, and hydrogen, followed by a raft of others such as chlorine, fluorine, bromine, sulfur, calcium, sodium, barium, strontium, nickel, copper, and cobalt. Despite the presence of metals such as copper and nickel, compounds containing these can still be termed organic. What about the term chromophore? Well, something in the organic compound has to be responsible for creating the color by the selective absorbance of light. The chromophore is simply the part of the molecule that is responsible for that absorbance. Not all of the parts of the molecule participate equally in this function. The easy part of the title is diketopyrrolopyrrole: this is simply a particular chromophore which for the rest of the discussion will be abbreviated as DPP. The simplest molecule which has a DPP chromophore has the chemical formula C_(18)N_2O_2H_(12). This is not a very big chromophore; in comparison, some other molecules about this size are common sugars and calcium stearate, the latter of which might be used in your laboratory or plant as a dispersant or lubricant in the compounding of plastics. The last part is the word model; why is DPP a model chromophore? DPP is a good model for the organic chromophores because many of the properties of chromophores and the pigments which are derived from them are exhibited by the family of colorants generically called the DPP's.
机译:由于本文旨在介绍有机颜料的一些基础知识,因此从头开始全面理解标题本身。首先,有必要认识到在整个色彩体验中,我们将尝试了解有关该体验的一小部分的几点:小,固体,通常为晶体颗粒,放入塑料后仍不溶并且有选择地吸收某些波长的光(因此看起来有颜色)。第二,有机是什么意思?有机是指以碳为基础的元素,但随后排除了某些碳化合物。也许这不是最好的定义,但是完整的解释可能会很冗长。包含其他元素对于产生有色化合物是必要的。对于有机着色剂,最可能存在的其他元素是氮,氧和氢,其次是许多其他元素,例如氯,氟,溴,硫,钙,钠,钡,锶,镍,铜和钴。尽管存在诸如铜和镍之类的金属,但是包含这些金属的化合物仍可以称为有机物。生色团一词怎么样?嗯,有机化合物中的某种成分必须通过光的选择性吸收来产生颜色。发色团只是分子中负责吸收的部分。并非分子的所有部分均平等地参与该功能。标题中最简单的部分是diketopyrrolopyrrole:这只是一种特定的生色团,在其余的讨论中将其简称为DPP。具有DPP发色团的最简单分子的化学式为C_(18)N_2O_2H_(12)。这不是一个很大的生色团。相比之下,这种大小的其他一些分子是常见的糖和硬脂酸钙,后者在您的实验室或工厂中可能用作塑料混合中的分散剂或润滑剂。最后一部分是单词模型; DPP为什么是模型发色团? DPP是有机发色团的一个很好的模型,因为发色团和衍生自它们的颜料的许多特性都被通常称为DPP的着色剂家族所展现。

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