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Back to the Basics of Organic Pigments: Diketopyrrolopyrrole Pigments as the Model Organic Chromophore

机译:回到有机颜料的基础:Diketopyropyrole颜料作为模型有机发色团

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Since this paper is meant to cover some of the fundamentals of organic pigments, let the start be a thorough understanding of the title itself. First, it is necessary to appreciate that of the entire universe of the color experience we are going to try to understand just a few points about a very small subset of this experience: small, solid, usually crystalline particles which remain insoluble when put into plastic and which selectively absorb light of certain wavelengths (hence appearing to have color). Second, what do we mean by organic? Organic means containing as a basis the element carbon, but then some carbon compounds are excluded. Perhaps this isn't the best of definitions, but a full explanation could be quite lengthy. Inclusion of other elements is necessary to create colored compounds. For the organic colorants, the most likely other elements present are nitrogen, oxygen, and hydrogen, followed by a raft of others such as chlorine, fluorine, bromine, sulfur, calcium, sodium, barium, strontium, nickel, copper, and cobalt. Despite the presence of metals such as copper and nickel, compounds containing these can still be termed organic. What about the term chromophore? Well, something in the organic compound has to be responsible for creating the color by the selective absorbance of light. The chromophore is simply the part of the molecule that is responsible for that absorbance. Not all of the parts of the molecule participate equally in this function. The easy part of the title is diketopyrrolopyrrole: this is simply a particular chromophore which for the rest of the discussion will be abbreviated as DPP. The simplest molecule which has a DPP chromophore has the chemical formula C_(18)N_2O_2H_(12). This is not a very big chromophore; in comparison, some other molecules about this size are common sugars and calcium stearate, the latter of which might be used in your laboratory or plant as a dispersant or lubricant in the compounding of plastics. The last part is the word model; why is DPP a model chromophore? DPP is a good model for the organic chromophores because many of the properties of chromophores and the pigments which are derived from them are exhibited by the family of colorants generically called the DPP's.
机译:由于本文旨在介绍一些有机颜料的基本面,让一开始是标题本身的透彻理解。首先,有必要认识到,我们要试着去了解一下这方面的经验非常小的子集只是几个点的色彩体验整个宇宙的:小,固体,通常结晶颗粒放入塑料时保持不溶性和选择性地吸收光的某些波长的(因此出现有颜色)。其次,我们怎么通过有机是什么意思?含有作为基础元素碳有机手段,但随后一些碳化合物被排除在外。也许这是不是最好的定义,而是一个完整的解释可能会很长。其它元素的夹杂物是必要创建有色化合物。对于有机着色剂,最有可能的其它元件呈现为氮,氧,和氢,随后其他如氯,氟,溴,硫,钙,钠,钡,锶,镍,铜和钴的筏。尽管金属如铜和镍,包含这些化合物的存在仍然可以称为有机的。什么术语发色?那么,东西在有机化合物具有负责产生由光的选择性吸收的颜色。发色很简单,就是负责吸光度分子的一部分。并非所有的分子的部分在此功能中平等参与。标题的容易的部分是二酮吡咯并吡咯:这只是一个特定的发色团的讨论的其余部分将被简称DPP。具有DPP发色团的最简单的分子具有化学式C_(18)N_2O_2H_(12)。这不是一个非常大的发色团;相比较而言,这个尺寸一些其他分子是常见的糖和硬脂酸钙,其中后者可能在实验室或植物可以用作塑料的配混的分散剂或润滑剂。最后一部分是词模型;为什么是民进党的典范发色?民进党是有机发色团一个很好的模式,因为许多发色团性质且由其衍生的颜料是由色料的家庭统称为民进党的表现。

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