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Environmentally Acceptable Cement Fluid Loss Additive

机译:环保水泥失水添加剂

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The need for environmentally acceptable cement additives hasrnencouraged the development of new additives based onrnbiopolymers, especially in the North Sea area wherernenvironmental regulations are very strict. The main challengernis to develop environmentally acceptable chemicals that meetrnthe relevant environmental legislation and operationalrncriteria, and thus could replace synthetic materials that arerncurrently being used. This paper will describe the developmentrnof a cement fluid loss additive that meets the challengesrndescribed above.rnCellulose-type materials have been used for decades asrnadditives to control cement fluid loss. These are PLONORrn(pose little or no risk) listed materials, which means they dornnot have to be subjected to testing protocols. They werernagreed upon by all OSPARCOM (Oslo-Paris Commission)rncountries, and thus, required no further extensive ecotoxicityrntesting before introduction. However, cellulose-type materialsrnthat have been used so far have several limitations: their fluidrnloss control properties decrease at temperatures above 200°F,rntheir salt tolerance is limited and over-retardation problemsrncan occur at low temperature. Furthermore, the slurry viscosityrnto fluid loss ratio is unfavorable compared to that of currentlyrnavailable synthetic fluid loss additives. When these celluloserntype materials are combined with other additives to helprnimprove their performance, the environmental advantages arerncompromised, and the resulting substance can no longer bernlisted as PLONOR.rnThis paper describes the development of a modifiedrncellulose (HEC) type of cement fluid loss product. It is saltrntolerant, it can perform well up to temperatures as high asrn280oF and is environmentally acceptable. After extensivernlaboratory testing, the production has been scaled up forrnintroduction and a successful field trial has been performed inrnthe North Sea area.
机译:对环境可接受的水泥添加剂的需求鼓励了基于生物聚合物的新型添加剂的开发,特别是在环境法规非常严格的北海地区。开发符合相关环境法规和操作标准的环境可接受的化学品的主要挑战者,因此可以替代目前正在使用的合成材料。本文将描述能克服上述挑战的水泥失水添加剂的开发。纤维素类型的材料已被用作控制水泥失水数十年的添加剂。这些都是PLONORrn(风险很小或没有风险)列出的材料,这意味着它们不必受到测试协议的约束。所有OSPARCOM(奥斯陆-巴黎委员会)国家都对它们进行了协商,因此在引入之前不需要进行进一步的广泛的生态毒性测试。但是,迄今为止使用的纤维素类材料有一些局限性:在高于200°F的温度下其流失控制性能下降,其耐盐性受到限制,并且在低温下可能出现过度延迟的问题。此外,与目前可用的合成失水添加剂相比,浆料的粘度对失水率是不利的。当这些纤维素类材料与其他添加剂组合以帮助改善其性能时,其环境优势将受到损害,并且所得到的物质将不再被列为PLONOR。它是耐盐的,在高达asr280oF的温度下仍能很好地工作,并且是环保的。经过广泛的实验室测试后,该产品已扩大规模,并已在北海地区进行了成功的现场试验。

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