CATALYTIC REDUCTION OF 1,6-DIHALOALKANES WITH ELECTROGENERATED NICKEL(I) SALEN IN DIMETHYLFORMAMIDE

机译：电生镍（I）硒代二甲基甲酰胺催化还原1,6-二卤代烷

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Using a previously established procedure for the formation of aldehydes via the reduction of primary alkyl monohalides by electrogenerated nickel(I) salen, the reaction between 1,6-dibromohexane and nickel(I) salen in dimethylformamide (DMF) was found unexpectedly to give cyclohexane in up to 75% yield, whereas 1-hexanal was formed in only a 5-6% yield, along with 1-dodecanal (1-3%) and none of the desired dialdehyde.

机译：使用先前建立的通过电生成的镍（I）沙伦还原伯烷基单卤化物形成醛的方法，出乎意料地发现1,6-二溴己烷与镍（I）沙伦在二甲基甲酰胺（DMF）中的反应出乎意料地生成了环己烷最多可以得到75％的收率，而仅以5-6％的收率形成1-己醛，以及1-十二碳三烯醛（1-3％），却没有所需的二醛。

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《Proceedings vol.2004-10; International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda and Meeting of the Electrochemical Society; 20040509-14; San Antonio,TX(US)》|2004年|P.37-40|共4页
会议地点 San AntonioTX(US)
作者
Parichatr Vanalabhpatana; Dennis G. Peters;
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Department of Chemistry, Indiana University, Bloomington, IN 47405 (U.S.A.);

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原文格式 PDF
正文语种 eng
中图分类电化学、电解、磁化学;
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2. HOMOGENEOUS CATALYTIC REDUCTION OF ALPHA,OMEGA-DIHALOALKANES WITH ELECTROGENERATED NICKEL(I) SALEN [J] . Mubarak MS., Peters DG. Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 1995,第1a2期

机译：电解镍（I）SALEN均相催化还原α，ω-二卤代烷基
3. Catalytic reduction of 1,2,5,6,9,10-hexabromocyclododecane by nickel(I) salen electrogenerated at vitreous carbon cathodes in dimethylformamide [J] . Elizabeth R. Wagoner, Clark P. Baumberger, Benjamin H. R. Gerroll, Electrochimica Acta . 2014,第Null期

机译：在二甲基甲酰胺中由玻璃碳阴极电生成的镍（I）Salen催化还原1,2,5,6,9,10-六溴环十二烷
4. CATALYTIC REDUCTION OF 1,6-DIHALOALKANES WITH ELECTROGENERATED NICKEL(I) SALEN IN DIMETHYLFORMAMIDE [C] . Parichatr Vanalabhpatana, Dennis G. Peters International Manuel M. Baizer Symposium in Honor of Dennis H. Evans and Masao Tokuda . 2004

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5. Development of a chemical means to mimic nucleo-cytoplasmic transport and catalytic reduction of secondary alkyl monohalides by cobalt(I) salen and nickel(I) salen electrogenerated at vitreous carbon electrodes. [D] . Bird, Sean Patrick. 2016

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6. Ultrasound-Assisted Hydrazine Reduction Method for the Preparation of Nickel Nanoparticles Physicochemical Characterization and Catalytic Application in Suzuki-Miyaura Cross-Coupling Reaction [O] . Adél Anna Ádám, Márton Szabados, Gábor Varga, 2020

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8. Carbon Dioxide Reduction via Homogeneous Catalytic Synthesis and Hydrogenation of N,N-Dimethylformamide [R] . Schreiner, S., Yu, J. Y., Vaska, L. 1988

机译：通过均相催化合成和N，N-二甲基甲酰胺的氢化还原二氧化碳

CATALYTIC REDUCTION OF 1,6-DIHALOALKANES WITH ELECTROGENERATED NICKEL(I) SALEN IN DIMETHYLFORMAMIDE

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