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Preparation, Characterization and Comparison of Thermal Properties of Aromatic Polyether Imides

机译:芳族聚醚酰亚胺的制备,表征及热性能比较

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摘要

Two aromatic polyimides were prepared by two-step way. Firstly, the poly (amic acid) s were synthesized from 1,3-bis (4-aminophenoxy) benzene and two aromatic dianhydrides. Secondly, polyimides were prepared via thermal imidization of poly (amic acid) precursors. The polyimides prepared were insoluble in common organic solvents such as tetrahydrofuran, chloroform and N, N-dimethylformamide. The inherent viscosities of poly (amic acid) s were 1.82dL/g and 2.67dL/g. Experimental results indicated that the resulting polyimides showed exceptional thermal properties with excellent thermal stability and higher glass-transition temperature in nitrogen.
机译:通过两步法制备了两种芳族聚酰亚胺。首先,由1,3-双(4-氨基苯氧基)苯和两种芳香族二酐合成聚(酰胺酸)。其次,通过对聚(酰胺酸)前体进行热酰亚胺化来制备聚酰亚胺。制备的聚酰亚胺不溶于常见的有机溶剂,例如四氢呋喃,氯仿和N,N-二甲基甲酰胺。聚(酰胺酸)的固有粘度为1.82dL / g和2.67dL / g。实验结果表明,所得的聚酰亚胺在氮中显示出优异的热性能,具有出色的热稳定性和较高的玻璃化转变温度。

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