Electrowinning of cobalt from chloride solution - A pilot plant study

摘要

An electrowinning pilot plant has been constructed at Falconbridge Nikkelverk A/S, Kristiansand, Norway. The equipment consists of a mixing tank where the electrolyte composition and temperature are controlled, an electrowinning tank equipped with five cathodes and six anodes of commercial size and design and a dechlorination facility. Electrowinning experiments were carried out in this pilot plant using acid cobalt chloride solution from the cobalt tankhouse. Key parameters were varied to obtain an improved understanding of the cobalt electrowinning process, focusing on the detrimental deposition of cobalt oxide on dimensionally stable anodes. The extent of anode scaling was found to be dependent on the electrowinning conditions. Low pH, temperature and cobalt concentration resulted in less scale being formed, however at the expense of cobalt current efficiency and cell voltage, adversely affecting electrowinning production capacity and energy consumption. When operating at high acidity, pH in the anolyte was higher than in the catholyte, which is believed to be due to H~+ ions taking part in the current transport across the diaphragm, migrating out of the bags surrounding each anode.