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Oxygen Diffusion in Donor Doped SrTiO_3: Influence of Thermal Pretreatment

机译:施主掺杂SrTiO_3中的氧扩散:热预处理的影响

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摘要

~18O tracer diffusion in Nb and La doped SrTiO_3 single crystal material under oxidising conditions has been investigated by Secondary Ion Mass Spectrometry (SIMS). The oxygen transport is sensitive to the duration of a preceding annealing step which is necessary in order to establish thermodynamic equilibrium between the specimens (which are in a reduced state as received) and the surrounding oxygen partial pressure. The diffusion profiles exhibit surface ~18O plateaus of significant depth; the plateaus are the more pronounced the lower the donor content, and the longer the pre-annealing step are. There is no influence of the donor type (Nb~5+ or La~3+).
机译:通过二次离子质谱(SIMS)研究了在氧化条件下Nb和La掺杂的SrTiO_3单晶材料中〜18O的示踪扩散。氧气传输对之前的退火步骤的持续时间很敏感,这对于在样品(接收时处于还原状态)和周围的氧气分压之间建立热力学平衡是必要的。扩散曲线显示出约18O的深度平台。平台越显着,供体含量越低,预退火步骤越长。施主类型(Nb〜5 +或La〜3 +)没有影响。

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