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Comparison of Fe/Al_2O_3 and Fe,Co/Al_2O_3 catalysts used for production of carbon nanotubes from acetylene by CCVD

机译:Fe / Al_2O_3与Fe,Co / Al_2O_3催化剂用于乙炔CCVD生产碳纳米管的比较

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Characterization of iron containing alumina supported catalysts was performed by TEM, Mossbauer and XPS spectroscopy during formation of multiwall carbon nanotubes from acetylene at 1000 K. TEM images showed that carbon fibers (outer diameter is around 20-40 nm) were generated on Fe/Al_2O_3 samples while on the bimetallic Fe,Co/Al_2O_3 carbon nanotubes with an average diameter of 8-12 nm were formed. XPS spectra revealed that Fe-Co alloy formed during the interaction of Fe,Co/Al_2O_3 and acetylene at 1000 K. The formation of the bimetallic alloy was proven by Mossbauer spectroscopy as well.
机译:通过乙炔在1000 K下形成多壁碳纳米管的过程中,通过TEM,Mossbauer和XPS光谱对含铁的氧化铝负载的催化剂进行了表征。TEM图像显示在Fe / Al_2O_3上生成了碳纤维(外径约为20-40 nm)。在双金属Fe,Co / Al_2O_3碳纳米管上形成平均直径为8-12 nm的样品。 XPS光谱表明,Fe-Co合金是在Fe,Co / Al_2O_3和乙炔在1000 K的相互作用中形成的。双金属合金的形成也由Mossbauer光谱法证明。

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