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Synthesis and Characterization of 3,6-di(nitramino)-1,2,4,5-tetrazines

机译：3,6-二（硝胺基）-1,2,4,5-四嗪的合成与表征

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The synthesis of 3(6)-nitramino-1,2,4,5-tetrazines via nitration of 3,6-disubstituted s-tetrazines with nitric acid is reported. The effect of 3(6)-amino-1,2,4,5-tetrazine structure and nitric acid concentration on the direction of the nitration reaction is shown. The synthesized products have been characterized by IR, UV, NMR spectroscopy, and DSC analysis.

机译：据报道，通过3,6-二取代的s-四嗪与硝酸的硝化反应合成了3（6）-nitramino-1,2,4,5-tetrazines。显示了3（6）-氨基-1,2,4,5-四嗪结构和硝酸浓度对硝化反应方向的影响。合成产物已通过IR，UV，NMR光谱和DSC分析进行了表征。

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来源
《》|2011年|p.3-7|共5页
会议地点 Nanjing(CN);Nanjing(CN)
作者
RUDAKOV G.F.; USTINOVA T.V.; ZHILIN V.F.;
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作者单位

Mendeleev University of Chemical Technology,9 Miusskaya Square,Moscow 125047,Russia;

Mendeleev University of Chemical Technology,9 Miusskaya Square,Moscow 125047,Russia;

Mendeleev University of Chemical Technology,9 Miusskaya Square,Moscow 125047,Russia;

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原文格式 PDF
正文语种 eng
中图分类爆炸物工业、火柴工业;爆炸物工业、火柴工业;爆炸物工业、火柴工业;
关键词
3,6-disubstituted 1,2,4,5-tetrazines; nitration; nitramines; thermal stability;

机译：3,6-二取代的1,2,4,5-四嗪;硝化;硝胺;热稳定性;

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1. Synthesis of 3,6-di(pyridin-2-yl)-1,2,4,5-tetrazine (pytz) capped silver nanoparticles using 3,6-di(pyridin-2-yl)-1 ,4-dihydro-1,2,4,5-tetrazine as reducing agent: Application in naked eye sensing of Cu~(2+), Ni~(2+) and Ag~+ ions in aqueous solution and paper platform [J] . Suvendu Samanta, Sudipto Das, Papu Biswas Sensors and Actuators . 2014,第octa期

机译：使用3,6-二（吡啶-2-基）-1,4-二氢-合成3,6-二（吡啶-2-基）-1,2,4,5-四嗪（pytz）封端的银纳米粒子1,2,4,5-四嗪为还原剂：在肉眼检测水溶液和纸平台中的Cu〜（2 +），Ni〜（2+）和Ag〜+离子
2. Superbase-Catalyzed [4+2]Cycloaddition of Acetylenes to 3,6-Di(pyrrol-2-yl)-1,2,4,5-tetrazine: A Facile Synthesis of 3,6-Di(pyrrol-2-yl)pyridazines [J] . Boris A. Trofimov, Tatyana E. Glotova, Dmitrii A. Shabalin Advanced synthesis & catalysis . 2013,第8期

机译：超碱催化的[4 + 2]乙炔与3,6-二（吡咯-2-基）-1,2,4,5-四嗪的环加成反应：3,6-二（吡咯-2-基）的简便合成哒嗪
3. Synthesis and characterization of 3,6-bis( 1 H-1,2,3,4-tetrazol-5-ylamino)-1,2,4,5-tetrazine (BTATz): Novel high-nitrogen content insensitive high energy material [J] . A. Saikia, R. Sivabalan, B.G. Polke, Journal of Hazardous Materials . 2009,第1期

机译：3,6-双（1 H-1,2,3,4-四唑-5-基氨基）-1,2,4,5-四嗪（BTATz）的合成与表征：新型高氮含量不敏感的高能材料
4. Synthesis and Characterization of 3,6-di(nitramino)-1,2,4,5-tetrazines [C] . RUDAKOV G.F., USTINOVA T.V., ZHILIN V.F. International seminar on propellants, explosives and pyrotechnics . 2011

机译：3,6-二（硝基氨基）-1,2,5-四嗪的合成与表征
5. Modification and Synthesis of Polymers by Inverse Electron Demand Diels Alder (iEDDA) Reaction of 1,2,4,5-Tetrazines [D] . Sun, Wenmo. 2021

机译：通过逆电子需求Diels桤木（IEDDA）反应的改性和合成聚合物1,2,4,5-四嗪的反应
6. N,N′-Bis(2,6-diisopropylphenyl)-3,6-dimethyl-1,2,4,5-tetrazine-1,4-dicarboxamide [O] . Na-Bo Sun, Guo-Wu Rao, Li-Ling Zhang 2015

机译：N，N'-双（2,6-二异丙基苯基）-3,6-二甲基-1,2,4,5-四嗪-1,4-二甲酰胺
7. Structures of 3,6-dimethoxy-1,2,4,5-tetrazine(V) and 3,6-Bis(1-aziridinyl)-1,2,4,5-tetrazine(VI) [O] . Krieger, Claus, Fischer, Hans, Neugebauer, Franz A., 1987

机译：3,6-二甲氧基-1,2,4,5-四嗪（V）和3,6-双（1-氮丙啶基）-1,2,4,5-四嗪（VI）的结构
8. Improved Synthesis and Properties of 3,6-Diamino-1,2,4,5-Tetrazine and 3,6-Dihydrazino-1,2,4,5-Tetrazine. [R] . Coburn, M. D., Ott, D. G., Stine, J. R., 1989

机译：改进了3,6-二氨基-1,2,4,5-四嗪和3,6-二肼基-1,2,4,5-四嗪的合成和性质。

Synthesis and Characterization of 3,6-di(nitramino)-1,2,4,5-tetrazines

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