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Physicochemical properties of 2,2-dinitro-1,3-bis-nitrooxy-propane

机译:2,2-二硝基-1,3-双硝基氧基 - 丙烷的物理化学性质

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Physicochemical properties 2,2 dinitro-1,3-bis-nitrooxy-propane have been studied. The glass temperature, temperature and enthalpy of thermal decomposition, saturated vapor pressure and enthalpy of evaporation, thermal stability of 2,2 dinitro-1,3-bis-nitrooxy-propane have been determined using differential scanning calorimeter and thermogravimetric analysis module. The glass temperature is -81°C. The temperature and enthalpy of decomposition are 193°C and 342 J/g. An equation has been derived for the constant of 2,2 dinitro-1,3-bis-nitrooxy-propane thermal decomposition. Factor k_0= 6.32×10~(12) s~(-1) and activation energy of thermal decomposition E =130.97 kJ/mol. The 2,2 dinitro-1,3-bis-nitrooxy-propane are completely thermodynamically compatible with polyurethane, divinylnitrile rubbers and polyvinilnitrate.
机译:已经研究了物理化学特性2,2 Dinitro-1,3-双 - 硝基氧基丙烷。玻璃温度,温度和蒸发焓和蒸发焓,使用差示扫描量热计和热重分析模块确定了2,2个二硝基-1,3-双 - 硝基氧基 - 丙烷的热稳定性。玻璃温度为-81°C。分解的温度和焓为193°C和342J / g。已经为2,2个二硝基-1,3-双 - 硝基氧基 - 丙烷热分解的常数衍生出一个等式。因子K_0 = 6.32×10〜(12)S〜(-1)和热分解的激活能量E = 130.97 kJ / mol。 2,2位二硝基-1,3-双 - 硝基氧基 - 丙烷与聚氨酯,二乙烯基腈橡胶和聚乙烯完全相容。

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