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Iron Contamination and Local Distribution within a 50 Cm Single-Channel Proton Exchange Membrane Water Electrolysis Cell

机译:50cm单通道质子交换膜水电解电池中的铁污染和局部分布

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Proton exchange membrane water electrolysis (PEMWE) will play a major role in the clean and versatile energy conversion in the near future. Offering scalable solutions of PEMWE are of high industrial interest and have to provide a sufficient durability and reliability. To achieve this, a better understanding of the impact of contamination on the PEMWE performance is very crucial. In this context, the membrane electrode assembly (MEA) is susceptible to several degradation processes like metallic cations (Fe~(3+/2+) stemmed from tubing). In particular, soluble and reduced iron species forming by Fenton reaction might attack via radicals the MEA. Hence, analyzing impurities and their resulting impacts on e.g. the proton transport resistance and degradation mechanisms at different length scales and local distributions are of large interest.
机译:质子交换膜水电解(PEMWE)将在不久的将来在清洁和多功能能量转换中发挥重要作用。 提供PEMWE的可扩展解决方案具有高工业利益,并且必须提供足够的耐用性和可靠性。 为此,更好地了解污染对PEMWE性能的影响非常重要。 在这种情况下,膜电极组件(MEA)易于若干劣化方法,如金属阳离子(Fe〜(3 + / 2 +)源于管道)。 特别是,由Fenton反应形成的可溶性和还原的铁物种可能通过自由基攻击MEA。 因此,分析杂质及其导致的影响。 不同长度尺度和局部分布的质子传输性和降解机制具有很大的兴趣。

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